1. Introduction to Alnico Alloys
Alnico (Aluminum-Nickel-Cobalt) alloys are a class of permanent magnet materials developed in the early 20th century, renowned for their excellent temperature stability and corrosion resistance. These alloys primarily consist of iron (Fe) as the base metal, with aluminum (Al, 8–12 wt%), nickel (Ni, 15–26 wt%), cobalt (Co, 5–24 wt%), and minor additions of copper (Cu) and titanium (Ti). Alnico magnets are categorized into isotropic and anisotropic variants, with the latter exhibiting superior magnetic properties due to directional crystal growth achieved through controlled solidification processes.
The magnetic performance of Alnico alloys is intrinsically linked to their crystal structure, phase composition, and microstructural features. This article explores the crystal structure of Alnico alloys, its formation mechanisms, and its profound impact on magnetic properties such as remanence (Br), coercivity (Hc), and magnetic energy product (BHmax).